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The Diocese of Pennsylvania is the second oldest diocese in the Episcopal Church. The first Bishop of PA, the Most Reverend William White, was also the first Presiding Bishop in the Episcopal Church as well as Chaplain to the Continental Congress. This historic diocese is comprised of 142 worshiping congregations located in the southeast portion of the state, throughout Philadelphia, Bucks, Montgomery, Delaware, & Chester counties.

The Episcopal Diocese of Pittsburgh, founded in 1865, covers the southwestern corner of Pennsylvania, including the current counties of Allegheny, Armstrong, Beaver, Butler, Cambria, Fayette, Greene, Indiana, Somerset, Washington, and Westmoreland. 

The Episcopal Diocese of Puerto Rico is headquartered in San Justo, and its Bishop Provisional is the Rt. Rev. Wilfrido Ramos-Orench.